enantioselective

enantioselective
(of a catalyst) that catalyzes the reaction of only one of a pair of enantiomers

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  • Enantioselective synthesis — Enantioselective synthesis: Sharpless epoxidation Enantioselective synthesis, also called chiral synthesis, asymmetric synthesis or stereoselective synthesis, is organic synthesis that introduces one or more new and desired elements of… …   Wikipedia

  • enantioselective reaction — enantioselektyvioji reakcija statusas T sritis chemija apibrėžtis Reakcija, kurios metu prochiralinio junginio didžioji dalis virsta vienu iš dviejų galimų enantiomerų. atitikmenys: angl. enantioselective reaction rus. энантиоселективная реакция …   Chemijos terminų aiškinamasis žodynas

  • enantioselective — en·an·tio·se·lec·tive in .ant ē ə sə lek tiv adj relating to or being a chemical reaction in which one enantiomer of a chiral product is preferentially produced en·an·tio·se·lec·tive·ly adv …   Medical dictionary

  • Aldol reaction — The aldol reaction is a powerful means of forming carbon–carbon bonds in organic chemistry.[1][2][3] Discovered independently by …   Wikipedia

  • Reacción aldólica — La reacción aldólica es una reacción química de formación de enlaces carbono carbono en química orgánica.[1] [2] [3] En su forma normal, la reacción aldólica involucra la adición nucleofílica del enolato de una cetona a un …   Wikipedia Español

  • Johnson–Corey–Chaykovsky reaction — The Johnson–Corey–Chaykovsky reaction (sometimes referred to as the Corey–Chaykovsky reaction or CCR) is a chemical reaction used in organic chemistry for the synthesis of epoxides, aziridines, and cyclopropanes. It was discovered in 1961 by A.… …   Wikipedia

  • Nucleophilic conjugate addition — is a type of organic reaction. Ordinary nucleophilic additions or 1,2 nucleophilic additions deal mostly with additions to carbonyl compounds. Simple alkene compounds do not show 1,2 reactivity due to lack of polarity, unless the alkene is… …   Wikipedia

  • Curtin–Hammett principle — The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett. It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is… …   Wikipedia

  • Organostannane addition — reactions comprise the nucleophilic addition of an allyl , allenyl , or propargylstannane to an aldehyde, imine, or, in rare cases, a ketone[1]. Organostannane addition to carbonyl groups constitutes one of the most common and efficient methods… …   Wikipedia

  • Michael reaction — The Michael reaction or Michael addition is the nucleophilic addition of a carbanion or another nucleophile[1][2][3] to an alpha, beta unsaturated carbonyl compound. It belongs to the larger class of conjugate additions. This is one of the most… …   Wikipedia

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