enantioselectivity

enantioselectivity
The selectivity of a reaction towards one of a pair of enantiomers

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  • enantioselectivity — en·an·tio·se·lec·tiv·i·ty sə .lek tiv ə tē, .sē n, pl ties the degree to which one enantiomer of a chiral product is preferentially produced in a chemical reaction …   Medical dictionary

  • Chiral Lewis acid — Chiral Lewis acids (CLAs) are a novel class of Lewis acid catalyst used in enantioselective asymmetric synthesis reactions which produce optically active products from optically inactive or impure starting materials. This type of preferential… …   Wikipedia

  • Corey-Itsuno reduction — The Corey Itsuno Reduction, also known as the Corey Bakshi Shibata (CBS) reduction, is a chemical reaction in which an achiral ketone is enantioselectively reduced to produce the corresponding chiral, non racemic alcohol. The oxazaborolidine… …   Wikipedia

  • Aldol reaction — The aldol reaction is a powerful means of forming carbon–carbon bonds in organic chemistry.[1][2][3] Discovered independently by …   Wikipedia

  • Curtin–Hammett principle — The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett. It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is… …   Wikipedia

  • Oxidation with dioxiranes — refers to the introduction of oxygen into organic molecules through the action of a dioxirane. Dioxiranes are well known for their oxidation of alkenes to epoxides; however, they are also able to oxidize other unsaturated functionality,… …   Wikipedia

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